I'm not sure about the order, but here are my вверх five:
Elena and Damon dance and Любовь scenes, "I don't think I've ever seen Ты еще alive." (4X07) Elena remembers Damon returning her ожерелье "I Любовь you, Elena." (4X01) Elena drinking from Damon "Blood sharing is kinda personal." (4X02) Damon and Elena постель, кровати and Любовь scene "I'm happy." (4X08) Damon talks to Elena about breaking the sire bond "I have to do the right thing, by you." (4X08)